碳纤维表面特征对碳/环氧复合材料界面性能影响研究

为了研究碳纤维表面特征与碳/环氧复合材料界面剪切强度的定量关系。采用扫描电子显微镜、比表面积分析仪、X射线光电子能谱仪对T800级碳纤维表面形貌、比表面积和表面化学特征进行了测试表征,并使用微珠脱粘法测试了复合材料的界面剪切强度（IFSS）。基于碳纤维比表面积测试结果,引入真实界面面积的概念,重点分析了界面面积和化学特征对IFSS的影响机理和规律。结果表明,不同表面状态的T800级碳纤维比表面积存在明显差异,两种除浆方法处理的碳纤维比表面积相差25.4%。消除界面面积影响的真实界面剪切强度（IFSS’）与碳纤维表面氧碳比呈现出较好的线性相关性,R2达到了0.94。反映出提高碳纤维比表面积和表面氧碳比是改善复合材料界面性能的有效手段。同时,也为定量研究碳纤维表面物理和化学特征对复合材料界面性能的影响提供了一种新的分析思路。     

高精度碳纤维复合材料副反射面天线制备工艺

文摘分析了模具选材、装配工艺过程及机加工工艺对高精度CFC副反射面天线制备的影响,研究了高精度CFC副反射面制备工艺的关键技术,进行了模具材料比较、装配工艺优化及机加工验证试验。结果表明,殷钢是制备高精度CFC副反射面天线的较理想模具材料;在夹层结构装配时采用外蒙皮原位装配技术并单独适配过渡区的蜂窝可有效避免天线型面精度超差;机加工辅助工装与三维摄影测量系统相结合的措施可有效确保装配基准点的高形位精度并大幅缩短天线加工周期。     

HS40碳纤维/氰酸酯树脂复合材料的湿热行为

通过对低温固化HS40碳纤维/氰酸酯树脂复合材料进行不同湿热环境处理以及3次循环吸湿-脱湿处理,研究其湿热行为。结果表明:复合材料在70℃水浸以及70℃/95%RH两种环境吸湿31 d饱和吸湿率分别为0.71%和0.11%,说明该低温固化氰酸酯树脂基复合材料有很好的耐湿热性;研究复合材料的循环吸湿-脱湿行为,发现复合材料在70℃水浴锅中第1次水浸10 d的吸湿率为0.69%,尚未达到饱和,而第2、3次水浸10 d后的吸湿率分别提高到0.72%和0.74%;复合材料的层间剪切强度随着循环次数的增加,降低更为明显,经过3次循环吸湿-脱湿之后试样的层间剪切强度较干态试样降低了50.77%,连续吸水60 d的试样层间剪切强度较干态试样降低了58.98%。     

高低频复合振动钻削CFRP/钛合金叠层结构试验

针对碳纤维增强复合材料（CFRP）和钛合金叠层结构在传统钻削过程中切削温度高、加工质量差等问题,基于低频振动钻削和高频（超声）振动钻削的优势,提出了高低频复合振动钻削的加工方法。采用自主研制的高低频复合振动钻削装置,对CFRP/钛合金叠层结构进行了制孔试验,对比研究了普通钻削、超声钻削、低频振动钻削和高低频复合振动钻削4种方式下的切削力、钛合金切屑形貌、切削温度和CFRP孔加工质量。结果表明：4种加工方式中,高低频复合振动钻削的轴向力波动相对较大,切削温度显著降低,产生的钛合金切屑呈不连续扇形且整体尺寸最小,CFRP孔出入口及孔壁的损伤程度最低,显著提高了加工质量,为复合材料叠层结构一体化制孔加工提供了指导意义。     

CFRP电流辅助铆接的连接域热响应建模与验证

钛合金铆钉变形时易不均匀、易开裂,在碳纤维增强树脂基复合材料（CFRP）铆接过程中引入脉冲电流作用,软化铆钉并改善其塑性。研究了连接域内的热响应机制与温度场分布,基于能量守恒、焦耳热定律、热传导定律构建了静态焦耳热模型表征稳态换热铆接工况下的CFRP温度,考虑铆接过程电流波动、温度分布不均和热区域分散性建立了动态温度场模型预测铆接过程温升。结果表明：CFRP孔周一定辐射半径范围处温度与钉中心温度线性相关,模型准确模拟出了40 s内的过程温度。静态模型在11%误差以内精准预测了中心饱和温度,动态模型模拟的温升趋势与实测温度值吻合较好。热量传递的滞后性使得动态模型对快速温升时的温度预测存在误差,该误差随电流密度变大而增加,最大达17.15%。接头损伤评估表明过程温度控制在150℃内时可获得质量合格的铆接接头。     

Wetting behavior of AgCu-4.5Ti filler reinforced by carbon nanotubes on C/C composite

The effect of Carbon Nanotubes (CNTs) content on the wettability of AgCu-4.5Ti + x CNTs (wt%) composite filler alloys on C/C composite was investigated. The results show that the added CNTs reacted with element Ti in the filler and produced the dispersed fine in situ synthesized TiC particles, which increased the consumption of element Ti and provided the nucleus for the growth of Ti-Cu compounds simultaneously. The above effects of introducing CNTs, inhibited the formation of Ti-Cu compounds, also changed the distribution of compounds, which dramatically influenced the interfacial microstructure and characteristics of wetting behavior. The increase of CNTs content refined and dispersed coarse Ti-Cu compounds, decreased the initial spreading temperature, and improved the wettability, but high content of CNTs (more than 0.3wt%) decreased the wettability of the filler alloy. The wetting interfacial microstructure of corresponding composite filler alloys were analyzed by Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectrometer (EDS) and Transmission Electron Microscope (TEM), which consisted of TiC, TiCu, TiCu₂ and TiCu₄ compound. The typical wetting behavior of AgCu-4.5Ti + 0.3wt% CNTs composite filler on C/C composite was divided into four stages. The effect mechanism of CNTs content on the wetting behavior was proposed.     

Laser joining of CFRTP to titanium alloy via laser surface texturing

Grid pattern was textured on Ti-6Al-4V alloy (TC4) substrate surface by nanosecond laser system. Laser joining of carbon fiber reinforced thermoplastic composite (CFRTP) to TC4 joints were performed, and the effect of texture grid depth was investigated. The contact angle of molten CFRTP on textured TC4 surface was measured and the tensile-shear force was tested. The fracture surface and interface morphology were observed. The results indicated that the wettability of molten CFRTP on TC4 surface improved remarkably after laser textured TC4. Shear force of CFRTP/TC4 joints was increased by 156% after laser textured TC4 surface. When the depth of grid was deeper than 100 μm, contact angle increased and incomplete filling of molten CFRTP in grid occurred, the shear force thus decreased gradually. Resin-carbon fibers mixture was adhered on the fracture surface of TC4, and the variation tendency of adhesion ratio was consistent with that of shear force. TC4 matrix was exfoliated from substrate and adhered at the fracture surface of CFRTP, indicating stronger mechanical interlocking occurred at the joining interface after laser textured TC4 surface. Beside mechanical interlocking, compound layer consisted of CTi_0.42V_1.58 carburization phase was also confirmed at interface, suggesting that chemical bonding also occurred at the joining interface.     

大尺寸CFRP固体火箭发动机壳体湿法缠绕用树脂配方研制

针对大尺寸炭纤维增强复合材料（CFRP）固体火箭发动机壳体的制备要求,研制了一种具 有良好粘度－温度及粘度－时间特性的炭纤维复合材料湿法缠绕成型树脂配方A。采用差示 扫描量热法（DSC）、傅立叶红外光谱（FT-IR）等分析技术对树脂基体的固化反应进行了系 统地研究,并测试了配方的粘度、力学性能及容器爆破强度。结果表明,该树脂配方A的反应 表观活化能为41.71 kJ／moL,室温下粘度低（≤0.5390 Pa·s）,适用期较长 （＞48 h ） ,不仅完全满足大尺寸CFRP固体火箭发动机壳体的湿法缠绕成型工艺要求,而且其树脂基体 及其炭纤维复合材料表现出优良的力学性能。炭纤维复合材料界面粘接良好,缠绕的
Φ150 mm容器的PV／W均大于48 km,纤维强度转化率达到89.0％以上。
     

碳纤维电阻率的评价表征

通过对QJ3074-1998中的测试原理和测试夹具的改进,提高了四探针法线材电阻率测试仪的测试精度并拓宽了测试范围,获得了试验验证.通过试样长度对测试结果的影响及试验条件对测试结果的影响等试验,系统评价表征了各种碳纤维的电阻率,为建立碳纤维电阻率测试方法标准奠定了重要的技术和数据基础.     

碳纤维复合材料低温热导率的实用计算方法

探讨和验证了碳纤维复合材料（ＣＦＲＰ）低温传热及低温热导率的一般规律、影响因素和计算方法;在分析讨论的基础上,总结归纳了热导率计算方法,并将计算结果与测试结果进行了比对,为设计、推算ＣＦＲＰ材料的低温热导率提出了实用的计算方法。